Search results for "Pressure generation"

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Discussion on “Experimental Deformation of Opalinus Clay at Elevated Temperature and Pressure Conditions: Mechanical Properties and the Influence of …

2021

AbstractThe testing procedure and results on saturated samples of Opalinus Clay in the work of Schuster et al. (Rock Mech Rock Eng https://doi.org/10.1007/s00603-021-02474-3, 2021) were conducted and presented using strain rates two to four orders of magnitudes higher than the rates needed to allow pore pressure equilibrium in the material, both in drained and undrained conditions. This leads to an erroneous estimation of the mechanical properties in saturated conditions. We discuss this aspect in the context of shale testing. We also discuss the effect of drying-induced fissuring on the mechanical properties of geomaterials tested in dry conditions.

Clay rock Desiccation cracks Micro-fissuring Opalinus Clay Pore pressure generation Rate-dependent mechanical behaviour ShaleSettore ICAR/07 - GeotecnicaClay rockGeologyContext (language use)Strain rateGeotechnical Engineering and Engineering GeologyPore water pressureTemperature and pressureGeotechnical engineeringDeformation (engineering)Oil shaleGeologyCivil and Structural EngineeringRock Mechanics and Rock Engineering
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Pressure effect investigations on spin-crossover coordination compounds

2018

International audience; The piezochromic properties of spin-crossover complexes have been recognized for a long time, with increasing pressure favouring the low spin state due to its smaller volume and therefore shifting the spin equilibrium towards higher temperatures and accelerating the relaxation at a given temperature. However, the interpretation and quantification of pressure-induced changes have been several times compromised by the relatively poor and incomplete spectral and structural information provided by the detection methods or due to the experimental difficulties related to the need for hydrostatic conditions at low temperatures. The present review is therefore primarily focu…

Materials scienceSpin statesGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural scienceslaw.inventionCoordination complexlawSpin crossoverQD[CHIM.COOR]Chemical Sciences/Coordination chemistryHigh-pressure chemistrySpin-½chemistry.chemical_classificationRelaxation (NMR)General Chemistry021001 nanoscience & nanotechnologySpin crossover0104 chemical sciencesVolume (thermodynamics)chemistryChemical physicsHydrostatic equilibrium0210 nano-technologyPressure generation
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